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Mineralogy

Geology (B.Sc) · Earth materials · free study notes for exams, placements and interviews

In short

Mineralogy is the study of naturally occurring, inorganic, crystalline solids with a definite chemical composition and ordered atomic structure — their crystallography, physical and optical properties, chemistry, structural classification, occurrence and uses. It is the foundation subject of a B.Sc Geology degree because every rock, ore body, soil and industrial raw material is described in terms of its constituent minerals. It is examined in university practicals (hand-specimen and thin-section identification), in GATE Geology (Section: Mineralogy and Crystallography), UPSC Geologist/Geo-Scientist (GSI, CGWB), and in the entry tests of the Geological Survey of India, Mineral Exploration and Consultancy Ltd (MECL), ONGC, Coal India, Hindustan Zinc, Vedanta, Tata Steel, JSW, UltraTech and cement/refractory companies. On the job it drives ore microscopy, mineral beneficiation decisions, XRD/XRF quality control and resource classification under the UNFC system used by the Indian Bureau of Mines.

Explained

What a mineral is, and how it is defined

Crystallography: lattices, symmetry and indices

Physical properties and how they are tested

Chemical mineralogy and classification

Optical mineralogy and instrumental identification

Economic and systematic mineralogy in the Indian setting

Key points

Formulas and examples

Miller indices: (h k l) = reciprocals of intercepts (p, q, r) in axial units, multiplied by their LCM to clear fractions. Intercept ∞ → index 0.
Bragg's Law (XRD): nλ = 2d sinθ — n = order of reflection (integer), λ = X-ray wavelength (Å; Cu-Kα = 1.5418 Å), d = interplanar spacing (Å), θ = half the diffraction angle 2θ (degrees).
Cubic d-spacing: d(hkl) = a / √(h² + k² + l²) — a = unit cell edge (Å).
Specific gravity: G = W_air / (W_air − W_water) — weights in the same unit (g); dimensionless.
Walker's steelyard: G = (a × W) / (b × (W − W₁)) form varies; more simply G = W/(W − W₁) with W₁ the apparent weight in water.
Birefringence: δ = n_ε − n_ω (uniaxial) or n_γ − n_α (biaxial); retardation Δ = t × δ, with t in nm (30,000 nm for a standard section) and Δ in nm giving the interference colour.
Density from cell content: ρ = (Z × M) / (N_A × V) — Z = formula units per unit cell, M = formula mass (g/mol), N_A = 6.022 × 10²³ /mol, V = unit cell volume (cm³).
Snell's law / RI: n = sin i / sin r = c/v; relief in thin section is judged against Canada balsam, n ≈ 1.537.
Molecular (weight) percentage of a metal: % metal = (atomic mass × number of atoms / formula mass) × 100.

Example 1 — Miller indices. A crystal face intercepts the a-axis at 2 units, the b-axis at 3 units and is parallel to the c-axis.

Example 2 — Metal content of an ore mineral. Calculate the Fe grade of pure haematite, Fe₂O₃ (Fe = 55.85, O = 16.00).

Example 3 — Bragg's law and cubic cell edge. A halite powder sample gives a first-order (n = 1) reflection from the (200) planes at 2θ = 31.70° with Cu-Kα radiation (λ = 1.5418 Å).

Example 4 — Specific gravity and density check. A galena specimen weighs 48.6 g in air and 42.1 g suspended in water.

Example 5 — Retardation and interference colour. A mineral grain in a standard 30 µm thin section shows a maximum birefringence of 0.021.

PropertyPyroxene (augite)Amphibole (hornblende)Mica (biotite)
StructureSingle chainDouble chainSheet
Cleavage2 at ~87°/93°2 at ~56°/124°1 perfect basal
Cross-sectionNearly square/octagonalDiamond/lozengeFlakes, elongate laths
Extinction angle~36-45°~12-34°~0-3°, bird's-eye mottling
Colour in PPLPale green-brown, weak pleochroismGreen-brown, strong pleochroismBrown, very strong pleochroism
HabitStubby prismsElongate prisms, needlesMicaceous, elastic
SystemAxes and anglesUniaxial/BiaxialTypical minerals
Cubica=b=c; 90°IsotropicGalena, garnet, halite, fluorite
Tetragonala=b≠c; 90°UniaxialZircon, rutile, cassiterite
Hexagonal/Trigonala=b≠c; γ=120°UniaxialQuartz, calcite, beryl, corundum
Orthorhombica≠b≠c; 90°BiaxialOlivine, barite, topaz
Monoclinicβ≠90°BiaxialGypsum, orthoclase, augite, hornblende
Triclinicall unequalBiaxialPlagioclase, microcline, kyanite

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Related topics

Igneous petrology · Sedimentary and metamorphic petrology · Crystallography and X-ray diffraction · Economic geology and ore deposits · Geochemistry · Engineering geology and construction materials

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