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Mixing and agitation

Chemical Engineering (B.E./B.Tech) · Fluid and particle mechanics · free study notes for exams, placements and interviews

In short

Mixing and agitation is the unit operation that uses a rotating impeller (or a static device) to create bulk flow and turbulence in a vessel so that composition, temperature, suspended solids, dispersed drops or gas bubbles become uniform. It decides blend time, heat-transfer coefficient, crystal size, reaction selectivity and fermenter oxygen supply, so almost every stirred reactor, blend tank, crystalliser, neutraliser and bioreactor is designed around it. In exams it is tested through standard tank geometry, the power number versus impeller Reynolds number curve, power and scale-up calculations, and Zwietering's just-suspended-speed correlation; GATE (CH) asks numerical power, N_P, N_Re and scale-up questions. Indian employers who test it include fertiliser and petrochemical majors, paints and specialty-chemical makers (Asian Paints, Pidilite, Atul, Aarti, SRF), pharma and biotech (Sun Pharma, Cipla, Biocon, Serum Institute) and process-equipment suppliers (Chemineer-type agitator vendors, L&T, Thermax).

Explained

What mixing means and how it is classified

Impellers, vessel geometry and flow patterns

Power consumption - the central correlation

Blend time, pumping capacity and mixing quality

Solid suspension, gas dispersion and heat transfer

Scale-up, mechanical design and Indian codes

Key points

Formulas and examples

N_P = P / (ρ N³ D⁵) - power number (dimensionless). P = power, W; ρ = density, kg/m³; N = impeller speed, rev/s; D = impeller diameter, m.
N_Re = ρ N D² / μ - impeller Reynolds number. μ = viscosity, Pa·s.
N_Fr = N² D / g - Froude number; g = 9.81 m/s².
Laminar: P = K_L μ N² D³ ; Turbulent (baffled): P = N_P ρ N³ D⁵
Q = N_Q N D³ - pumping capacity, m³/s; circulation time t_c = V/Q, s.
Tip speed = π N D, m/s ; Torque = P/(2πN), N·m.
Nθ = constant (turbulent) - θ = blend time, s.
N_js = S ν0.1 [g(ρ_s − ρ_L)/ρ_L]0.45 X0.13 d_p0.2 / D0.85 - Zwietering; ν = kinematic viscosity m²/s, X = mass of solid per 100 mass of liquid, d_p = particle size m, S = geometry factor.
Scale-up at equal P/V: N₂ = N₁ (D₁/D₂)2/3 ; equal tip speed: N₂ = N₁ (D₁/D₂)
ε = P/(ρV) - mean specific energy dissipation, W/kg; Kolmogorov scale η = (ν³/ε)0.25, m.
Power-law apparent viscosity at the impeller: μ_app = K (k_s N)n−1, k_s ≈ 11-13.
Gas-liquid: N_A = Q_g/(N D³) ; k_L a = C (P_g/V)α u_sβ.

Example 1 - Turbulent power draw of a Rushton turbine. A baffled tank, T = 1.8 m, holds water (ρ = 1,000 kg/m³, μ = 1.0 × 10⁻³ Pa·s) to H = T. A six-blade Rushton turbine, D = T/3 = 0.6 m, runs at 120 rpm = 2.0 rev/s. Take N_P = 5.5.

Example 2 - Laminar power in a viscous fluid. Same impeller (D = 0.6 m) at N = 0.5 rev/s in a resin of ρ = 1,100 kg/m³ and μ = 60 Pa·s. For this geometry K_L ≈ 71 (laminar constant for a Rushton turbine).

Example 3 - Scale-up at equal power per unit volume. A pilot tank of 0.05 m³ uses D₁ = 0.15 m at N₁ = 300 rpm (5 rev/s), N_P = 1.4 (45° PBT), ρ = 1,000 kg/m³. Scale geometrically to 5 m³ (volume ratio 100, so length ratio R = 1001/3 = 4.642), D₂ = 0.15 × 4.642 = 0.696 m.

Example 4 - Just-suspended speed (Zwietering). Sand (ρ_s = 2,600 kg/m³, d_p = 200 μm = 2 × 10⁻⁴ m) is suspended in water (ρ_L = 1,000 kg/m³, ν = 1 × 10⁻⁶ m²/s) at 10 kg solid per 100 kg water (X = 10). Tank T = 1.2 m, pitched-blade turbine D = 0.4 m, C = T/4, S = 6.0.

Example 5 - Gassed power and blend time in a fermenter. A 10 m³ fermenter (T = 2.2 m, H ≈ 2.7 m) has two Rushton turbines of D = 0.73 m at 110 rpm (1.833 rev/s) in broth of ρ = 1,020 kg/m³, μ = 2 × 10⁻³ Pa·s.

ImpellerFlowN_P (baffled, turbulent)N_QBest for
Rushton disc turbine (6 blade)Radial5.0-6.0~0.72Gas dispersion, high shear
Flat-blade paddleRadial1.5-2.5-Simple blending, viscous
45° pitched-blade turbine (4 blade)Axial/mixed1.3-1.50.72-0.79Solid suspension, blending, heat transfer
Hydrofoil (high-efficiency)Axial0.3-0.40.5-0.55Low-shear blending, large volumes
Marine propeller (pitch = D)Axial~0.35~0.5Small tanks, portable mixers
AnchorTangential0.3-0.5 (laminar, Re-dependent)-μ > ~20 Pa·s, wall heat transfer
Helical ribbonAxial, laminarK_L/N_Re (K_L ~ 150-350)-Very high viscosity, pastes
Scale-up basisN₂/N₁P/V ratioTip speed ratioBlend time ratio
Equal P/VR−2/31R1/3R2/3
Equal tip speedR−1R−11R
Equal blend time (Nθ)1R²R1
Equal Reynolds numberR−2R−4R−1R²

(R = D₂/D₁, geometric similarity, turbulent regime.)

Where it is used

Interview questions

Common mistakes

Related topics

Dimensional analysis and similitude · Fluid flow and pumps in process plants · Filtration, sedimentation and fluidisation · Heat transfer in jacketed and coiled vessels · Chemical reaction engineering: non-ideal flow and RTD · Mass transfer: gas absorption and aeration

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