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Printing substrates and inks: paper, board, films and ink chemistry

Printing and Packaging Technology (B.Tech) · Foundations · free study notes for exams, placements and interviews

In short

A print job is only as good as the surface it lands on and the fluid that lands on it. This topic covers the three substrate families — paper, paperboard/corrugated, and plastic films and foils — their structure, measurable properties and test methods, and the chemistry of printing inks: pigment, vehicle, solvent and additives, and how each ink dries or cures. It is examined in every Printing Technology syllabus (AICTE/CBCS "Printing Materials" or "Substrates and Inks" paper), and it is the single most practical area in interviews at Manipal Technologies, Thomson Press, Parksons/ITC PSPD, Huhtamaki, Uflex, Jindal Poly, TCPL, Essel Propack, Siegwerk, DIC, Flint and Hubergroup. On the job it decides paper indenting, reel costing, pouch yield, ink mileage and whether a laminate passes a food-contact or shelf-life test.

Explained

Paper and board: how they are made, and the grades that result

Paper and board properties, and how they are tested

Plastic films, foils and laminates

Ink chemistry: what is in the can

Ink by process: drying, curing and rheology

Substrate–ink interaction: printability and runnability

Standards, safety and Indian regulation

Key points

Formulas and examples

Grammage G = m/A (g/m²; m in g, A in m²). Sheet mass = G × length × width (m).
Ream (500 sheets) weight = 500 × G × L × W / 1000 kg
Bulk b = t/G (cm³/g, with t in cm and G in g/cm²); apparent density ρ = 1/b (g/cm³)
Reel length L = M / (G × w) (M = net mass kg, G = grammage in kg/m², w = reel width m)
Sheets required = (copies × sheets per copy) × (1 + spoilage fraction)
Moisture content % = (wet mass − oven-dry mass)/wet mass × 100
Burst factor BF = bursting strength (kgf/cm²) × 1000 / grammage (g/m²)
Film yield Y = 10⁶ / (t × ρ) (m²/kg; t in µm, ρ in kg/m³). Film grammage = t × ρ /1000 (g/m²)
Laminate grammage = Σ (layer grammages) + Σ (adhesive/coating gsm)
Permeability P = WVTR × t (g·mm/m²·day) — so WVTR₂ = WVTR₁ × t₁/t₂ for the same polymer
Ink mileage = 10⁶ / (wet film thickness in µm × ink density in kg/m³) (m² of inked area per kg)
Young's wetting condition γ_substrate ≥ γ_ink + 7 to 10 (mN/m, i.e. dyne/cm)
McKee box compression BCT(N) ≈ 8.59 × ECT(kN/m)0.746 × h(mm)0.254 × Z(mm)0.492, Z = box perimeter = 2(l+b). (The textbook constant 5.874 belongs to the lb/in–inch–lbf form of the same equation.)
Safe stacking load = BCT / safety factor (typically 3–6 for humidity, time and handling)

Example 1 — paper indenting and cost. A brochure job needs 20,000 printed sheets of 100 gsm coated art paper, sheet size 64 × 90 cm; allow 5% spoilage. Price ₹95/kg.

Example 2 — reel length and board bulk. (a) A newsprint reel of net mass 450 kg, 68 gsm, width 865 mm.

(b) A folding boxboard is 300 gsm with caliper 0.400 mm.

Example 3 — pouch yield and film cost. Structure: BOPET 12 µm (ρ 1,400) + adhesive 2 g/m² + metallised… use MET-PET 12 µm already counted; here BOPET 12 / adhesive 2 gsm / LDPE 50 µm (ρ 922). Pouch 150 × 220 mm, three-side seal, 10% trim and process waste. Laminate price ₹230/kg.

Example 4 — ink mileage for a gravure run. Wet film 2.5 µm, ink density 1,050 kg/m³, print area 50,000 m² at 60% average ink coverage. Ink ₹280/kg.

Example 5 — corrugated box strength. Board: bursting strength 2.8 kgf/cm², combined grammage 440 g/m², ECT 6.5 kN/m, caliper 4.2 mm. Box 450 × 350 mm, product 12 kg, stacked 5 high.

Example 6 — barrier scaling. A 25 µm BOPP has WVTR 6.0 g/m²·day at 38 °C/90% RH. Permeability = 6.0 × 0.025 = 0.15 g·mm/m²·day. A 20 µm film of the same polymer → WVTR = 0.15/0.020 = 7.5 g/m²·day. To reach 0.5 g/m²·day you would need 0.30 mm of BOPP — impractical, which is why a metallised or foil layer is used instead.

SubstrateTypical gaugeMoisture barrierOxygen barrierHeat sealTypical use
LDPE/LLDPE25–100 µmGoodPoorExcellentSealant layer, liners
BOPP15–30 µmGoodModerateNo (needs coex seal)Snack and biscuit face film
BOPET12–23 µmModerateModerateNoPrinted outer layer
Metallised PET12 µmVery goodVery goodNoSnacks, tea, dry mixes
Aluminium foil7–40 µmExcellent (>20 µm)ExcellentNoRetort, pharma blister/strip
Nylon (PA)15–25 µmPoorGoodNoVacuum packs, thermoform
Coated art paper70–300 gsm———Magazines, cartons, labels
Duplex/WLC board230–450 gsm———Mono-cartons
Paste ink (offset)Liquid ink (flexo/gravure)UV ink
Viscosity10–100 Pa·s, thixotropic50–500 mPa·s0.5–5 Pa·s
Measured byLaray/cone-and-plate, Inkometer tackDIN 4 or Zahn 2 flow cup (s)Cone-and-plate
DryingOxidation / heatsetSolvent or water evaporationPhoto-polymerisation
Film thickness1–2 µm1–3 µm (gravure 1–8)2–6 µm
Solvent/VOCLowHigh (recovery needed)Nil
Best forPaper, boardFilm, foil, board, paperFilm, labels, metal

Where it is used

Interview questions

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