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Bioenergy: biomass, biogas and biofuels

Energy / Renewable Energy Engineering (B.Tech) · Renewable energy technologies · free study notes for exams, placements and interviews

In short

Bioenergy is energy recovered from biomass - any recently living organic matter such as crop residue, wood, dung, molasses, municipal organic waste or algae - by burning it, converting it to a gas, or converting it to a liquid fuel. Unlike solar and wind it is carbon-based, dispatchable and storable, so it substitutes for coal in boilers, for LPG and CNG in cooking and transport, and for petrol and diesel in vehicles. India has roughly 750 million tonnes of biomass produced annually with about 230 million tonnes surplus, giving an assessed power potential near 28 GW (MNRE estimates; figures are revised periodically), and bioenergy policy is central to the ethanol blending programme, the SATAT compressed biogas scheme and paddy-stubble management in Punjab and Haryana. It is examined in GATE (Energy/ME/CH), university renewable energy papers and the energy sections of UPSC/ESE, and it is tested in interviews at Praj Industries, Thermax, Indian Oil, BPCL, HPCL, EID Parry, Balrampur Chini, Gail, NTPC and sugar-cogeneration companies.

Explained

Biomass: resource, properties and characterisation

Thermochemical conversion

  1. Direct combustion - complete oxidation with excess air in a grate-fired, fluidised-bed (BFB/CFB) or suspension-fired boiler, raising steam for a Rankine cycle. Typical biomass power plant efficiency is only 20-28% because of small size and modest steam parameters.
  2. Co-firing - biomass pellets fired with coal in existing thermal units. India's policy (MoP/CEA directions) mandates biomass pellet co-firing in coal-based plants - commonly cited at 5%, with a higher target announced for later years; the mandated percentage and dates have been revised more than once, so quote the current MoP revised policy rather than a fixed number.
  3. Gasification - partial oxidation at 700-1,200 °C with a sub-stoichiometric air (or O₂/steam) supply to give producer gas (CO 18-22%, H₂ 15-19%, CH₄ 1-5%, CO₂, N₂; LHV 4-6 MJ/m³ with air). Zones in a downdraft gasifier from the top: drying → pyrolysis → combustion (oxidation) → reduction.
    • Key reactions: C + O₂ → CO₂ (exothermic, supplies heat); Boudouard C + CO₂ ⇌ 2CO (endothermic); water-gas C + H₂O ⇌ CO + H₂; water-gas shift CO + H₂O ⇌ CO₂ + H₂; methanation C + 2H₂ ⇌ CH₄.
    • Types: updraft (counter-current - high tar, high thermal efficiency, suitable for direct heat); downdraft (co-current - gas passes through the hot oxidation zone and tar cracks, so lowest tar; standard for engine applications up to ~1 MW); cross-draft (fast response, charcoal); fluidised bed (bubbling/circulating - uniform temperature, scalable, fuel-flexible, moderate tar); entrained flow (large scale, syngas for chemicals).
    • Equivalence ratio (actual air / stoichiometric air) of about 0.2-0.3 is the gasification window; below it, pyrolysis dominates, above it, combustion. Tar is the main practical failure mode - it fouls cyclones, filters and engine valves; cleaning uses cyclone + scrubber + fabric/sand filter, or catalytic/thermal cracking.
    • Use: thermal (kilns, dryers), 100% producer-gas spark-ignition engines (derate ~50% of diesel rating), or dual-fuel diesel engines (60-80% diesel replacement).
  4. Pyrolysis - thermal decomposition at 400-600 °C without oxygen, giving char, condensable bio-oil and gas. Slow pyrolysis maximises charcoal; fast pyrolysis (very short vapour residence time, rapid quench) maximises bio-oil at 60-75%. Bio-oil is acidic (pH 2-3), oxygen-rich, high viscosity and unstable - it needs hydrodeoxygenation before use as a transport fuel.
  5. Torrefaction - mild pyrolysis at 200-300 °C; produces a dry, brittle, hydrophobic, grindable "bio-coal" with ~20-23 MJ/kg, suited to co-firing.
  6. Liquefaction / HTL - high pressure, 250-370 °C in water; handles wet feedstock without drying.

Biochemical conversion: biogas and anaerobic digestion

Liquid biofuels: ethanol, biodiesel and advanced fuels

Indian policy, institutions and economics

Key points

Formulas and examples

Energy content of fuel: E = m × CV, where m = mass (kg) and CV = calorific value (MJ/kg or kJ/kg). For gas, E = V × CV with V in m³ (at NTP) and CV in MJ/m³.
Dulong-type HHV (MJ/kg, mass fractions): HHV ≈ 33.8 C + 144.3 (H − O/8) + 9.4 S - approximate for high-oxygen biomass.
LHV = HHV − 2.442 × (9H + M), with H and M as mass fractions of hydrogen and moisture; 2.442 MJ/kg is the latent heat of water at 25 °C.
Equivalence ratio ER = (actual air supplied) / (stoichiometric air); gasification 0.2-0.3, combustion > 1.
Overall plant efficiency: η = electrical output / (fuel feed rate × CV); heat rate (kJ/kWh) = 3600 / η.
Gasifier cold-gas efficiency: η_cg = (V_gas × CV_gas) / (m_biomass × CV_biomass).
Biogas yield: V_biogas = m_feed × VS fraction × VS destroyed fraction × specific yield (m³/kg VS destroyed).
Digester volume: V_d = Q × HRT, where Q = daily slurry feed (m³/day) and HRT = hydraulic retention time (days).
Organic loading rate OLR = (Q × S₀) / V_d, in kg VS or COD per m³ per day.
Methane from COD: 0.35 m³ CH₄ per kg COD destroyed at STP (0.395 m³/kg at 35 °C).
Ethanol stoichiometry: C₆H₁₂O₆ → 2 C₂H₅OH + 2 CO₂, mass yield 92/180 = 0.511 kg ethanol per kg glucose.
Blend heating value: CV_blend = x·CV_bio + (1 − x)·CV_fossil, on the same volume or mass basis throughout.
Transesterification: 1 mol triglyceride + 3 mol methanol → 3 mol FAME + 1 mol glycerol; practical methanol:oil molar ratio 6:1.

Example 1 - Rice-husk power plant sizing. A plant burns 1 tonne/hour of rice husk of CV 14 MJ/kg at an overall efficiency of 24%. Find the electrical output and annual generation at 75% plant load factor.

Example 2 - Family biogas plant for a dairy household. Five cattle give 50 kg dung/day. Dung is diluted 1:1 with water; biogas yield is 0.036 m³ per kg of fresh dung; HRT = 40 days; biogas CV = 22 MJ/m³; a stove needs 0.25 m³/h.

Example 3 - COD-based methane from a distillery effluent. A distillery discharges 500 m³/day of spentwash at COD 100,000 mg/L; 80% COD is removed in a UASB reactor; 0.35 m³ CH₄/kg COD removed; biogas is 65% CH₄.

Example 4 - Ethanol from C-heavy molasses. A distillery processes 300 tonnes/day of C-heavy molasses containing 45% total fermentable sugars; fermentation and distillation efficiency is 88% of theoretical; ethanol density 0.789 kg/L.

Example 5 - E20 energy and mileage effect. Petrol CV ≈ 32 MJ/L, ethanol ≈ 21.1 MJ/L.

RouteFeedstockMain productTypical conversion conditionEfficiency / yield
CombustionAny dry biomassHeat/steamExcess air, 850-1,100 °C20-28% biomass-to-power
GasificationDry, sized, <20% moistureProducer gas 4-6 MJ/m³ER 0.2-0.3, 700-1,200 °C70-80% cold-gas
Fast pyrolysisDry, fine biomassBio-oil450-550 °C, ~1-2 s vapour time60-75% bio-oil
Anaerobic digestionWet, high-moisture, C/N 20-30Biogas 50-70% CH₄30-40 °C, pH ~7, HRT 30-50 d0.3-0.5 m³/kg VS added
FermentationSugar/starchEthanol30-32 °C, pH 4-5, yeast≤0.511 kg/kg sugar
TransesterificationVegetable/waste oilBiodiesel (FAME)55-65 °C, KOH, MeOH:oil 6:195-98% of oil mass
FuelCVComparison note
Biogas20-25 MJ/m³~55-60% CH₄; CNG is ~36-38 MJ/m³
Producer gas4-6 MJ/m³Air-blown; nitrogen-diluted, so engines derate
Ethanol26.8 MJ/kg, 21.1 MJ/LRON ~108; hygroscopic
Biodiesel37-40 MJ/kg~8% below diesel; cetane 48-60
Rice husk13-15 MJ/kg18-20% ash, silica-rich

Where it is used

Interview questions

Common mistakes

Related topics

Renewable energy systems: solar, wind and storage · Hydrogen and the energy transition · Small hydro, geothermal and ocean energy · Steam power plants and boilers · IC engines and alternative fuels · Environmental pollution control and waste management

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